Poly[[aqua­bis(μ3-isonicotinato-κ3 O:O′:N)tris­(μ2-isonicotinato-κ3 O,O′:N)(nitrato-κO)bis­(μ4-oxalato-κ6 O 1,O 2:O 2:O 1′,O 2′:O 1′)dierbium(III)tetra­silver(I)] tetra­hydrate]

نویسندگان

  • Yan-Mei Wen
  • Tian-Jun Feng
  • Li-Xin He
چکیده

In the title coordination polymer, {[Ag(4)Er(2)(C(6)H(4)NO(2))(5)(C(2)O(4))(2)(NO(3))(H(2)O)]·4H(2)O}(n), each Er(III) atom is coordinated in a bicapped trigonal-prismatic coordination geometry by three O atoms from two isonicotinate (IN) ligands, four O atoms from two oxalate ligands and one O atom from either a nitrate ion or a water mol-ecule, both of which are half-occupied over the same site. One Ag(I) atom has a Y-shaped geometry defined by one N atom from one IN ligand, one O atom from another IN ligand and one O atom from an oxalate ligand. The other Ag(I) atom is coordinated by two IN ligands and one O atom from an oxalate ligand. One of the IN ligands is disordered over an inversion center and forms a bridge between two centrosymmetric Ag(I) ions. Due to the disorder, this IN ligand coordinates to the Ag atom through either the pyridyl N or the carboxyl-ate O atoms. The IN and oxalate ligands link the Er and Ag atoms into a three-dimensional coordination framework. O-H⋯O and C-H⋯O hydrogen bonds are observed in the crystal structure.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009